Re: This works for me!!
Basically, what John said. I've got the same TY303 225/70/19. 5s on my truck. I run ... 55 rear and 65 front, unladen. Those pressures seem to yield the best handling. 62 in front is a little too soft, as the tires tend to slide a bit too much in hard turns (like running a 15 MPH hairpin turn at 25-30!) Any more pressure in the rear and the outside edges of the tread don't contact the pavement.
I haven't done any brake stands lately, but the tires don't seem to be walking on the wheels any more, since Matt and Dan used the new 'glue' when they re-did my tires last time. With the powder in them, they are staying as balanced and smooth as I can expect from a truck - that is, the ride is a little harsher than Dad's Town Car, and it has at least twice the range!
As to your tires, start at 65/55, and check the tread contact and handling in general. In 10K miles, you should be able to find the 'best' unladen pressure for your tires. Then when you apply a load to the truck, air up the tires so the 'bulge' looks about the same. A few short runs should let you dial in the laden pressure. Then write down them pressures for future reference.
I've got 75K on the tires now, and there're still lots of tread left. I might get 120K out of them, might get more. Time will tell.
Fest3er