Here are the ratios that I've cut/pasted from a popular OD manufacturer's website:
NV4500-
1st 5. 61
2nd 3. 04
3rd 1. 67
4th 1. 00
5th 0. 74
NV5600-
1st 5. 63
2nd 3. 38
3rd 2. 04
4th 1. 39
5th 1. 00
6th 0. 73
Comparing the 6 to the 5:
As you can see, 1st is practically the same. Second is slightly lower. Not much, but it you can tell it is easier for 2nd gear starts in the real world (personal experience). Notice the huge difference in the 2-3 split. Ever try to make a 2-3 shift in a 5 speed going up hill pulling a load? If you wind it out to 2500 rpm, the speed drops to just under 1400 rpm, almost a 50% drop. In a 6 speed the drop is to 1500. It's a difference you can really feel. On the 3-4 shift, the 5 speed goes from 2500 to 1500, the 6 speed from 2500 to 1700. Then you get a 39% drop to get into direct drive. O/D is practically the same.
I've rounded figures and there may be some math errors here, but you can see what I'm getting at.