Pressure doesn't have the same effect on reservoir type shocks as with air/oil emulsion type shocks.
It's the valving that determines the ride, not nitrogen pressure. There's a piston that separates the nitrogen from the oil, so when you pressurize the shock, you're pressurizing the oil as well, but the only outward force is directed towards an area the size of the diameter of the shock shaft. Not enough to notice a difference in ride. You really need to get different valving to make the ride smooth.
The main reason for pressurizing is to keep the shock piston from cavitating while moving through it's stroke. If you lower the pressure, the piston will cavitate and blow through its travel quite quickly. You may also hear a popping sound from your shocks.
Higher pressures usually result in a smoother riding shock
One thing to note, too, is that the KORE springs are stiffer than stock. If you got the complete kit, it stiffens the front and softens the rear.