TDRAdmin4
Staff Member
[RAW]<p>The cause and effect of the lower 2007 diesel emission requirements are far reaching. In this issue’s Member2Member, TDR writer Doug Leno will closely examine the changes to ultra low sulfur diesel (ULSD) fuel. To examine the changes to engine lube oils we contracted with a “hired gun,” John Martin, formerly (25 years of service) of Lubrizol Corporation. </p>
<p>For those not familiar with Lubrizol, Lubrizol is one of a handful of companies that make and sell the additive package that goes into the finished product, one gallon lube oil jug.</p>
<p>More on John’s credentials: He holds several patents and has published many industry-related technical articles. He is a past Chairman of the Cleveland Section of the Society of Automotive Engineers (SAE) and both a Recognized Associate and a Silver Spark Plug (their highest honor) of the Technology and Maintenance Council of the American Trucking Associations. He is a recognized lubrication consultant to both the racing (NASCAR and NHRA) and trucking industries. </p>
<p>We are fortunate to have John’s article addressing the CJ-4 lube oil specifications.</p>
<span class="columnheader"><p>CI-4/CJ-4 DIESEL OILS<br>
What's a Guy Supposed to Buy?</p>
</span>
<p class="columnheader">A new diesel engine oil (API CJ-4) becomes commercial before year end 2006. It is important that you understand what API CJ-4 lube oil is (and isn’t), and why it was developed. Armed with the proper knowledge imparted by someone who isn’t trying to sell you something, you can then make an intelligent decision about which oil to use in your diesel engine. </p>
<center>
<hr align="center" width="400">
<em>It is important that you understand what API CJ-4<br>
lube oil is (and isn’t), and why it was developed.<br>
</em>
<hr align="center" width="400" noshade>
</center>
<p> First, let's discuss why this new oil was developed. The EPA will tighten their exhaust emissions thumbscrew on diesel engines starting January 1, 2007, to reduce particualte matter (PM) and oxides of Nitrogen (NOx) emissions even further. To meet these latest requirements most diesel engine manufacturers are resorting to the use of diesel particulate filters (DPFs). A DPF differs from the catalytic converters we have used for years on gasoline engines in that a DPF actually filters the <em>entire</em> diesel exhaust stream. </p>
<p>On the surface you wouldn’t think this would be a big deal— Europeans have been using DPFs for years. The difference is that Europeans don’t accumulate mileage like Americans and they will tolerate much more frequent service intervals. Our EPA has decreed that the new DPFs must go 150,000 miles before needing removal for cleaning. This means the soot collected in the DPF must be burned off in the exhaust system frequently if trap life is to exceed 150,000 miles without removal and cleaning. </p>
<p>I don’t have to tell you that diesel exhaust is relatively dirty. It consists of lots of soot (That’s what turns your oil black!) and unburned residues from both the fuel and the oil. Sulfur in the fuel can significantly hamper DPF performance. That’s why we’re getting the new ultra low sulfur diesel (ULSD) fuel this fall (more about ULSD fuel later). Phosphorus and sulfur in the lube oil can shorten DPF cleaning intervals considerably. Phosphorus (P) can “glaze over” and plug the tiny holes in the DPF, making the openings effectively smaller and quicker to plug. Sulfur (S) can “mask” the DPF, making it temporarily less effective. Sulfated Ash (SA) in the lube is thought to build up deposits on the DPF over time. These deposits that originate from diesel fuel and lube oil then make the DPF effectively smaller and quicker to plug. </p>
<span class="columnheader"><p>A Little Lube Oil History</p></span>
<p>Before we talk about what the additive industry and the oil companies have done to meet the EPA’s latest directive, we need a brief lube oil history lesson. Years ago diesels were operated on refined crude oils containing virtually no additive chemistry. As power density increased oil companies found they needed to add specific chemical compounds to the oil to provide performance attributes that crude oils couldn’t deliver. The additive industry was born! </p>
<p>Traditionally, each new diesel engine oil specification was issued because available oils couldn’t provide the lube oil performance needed. For example, API CE was issued to create oils which solved an oil consumption problem in Cummins NTC-400 engines. For fifty years each new diesel engine oil specification meant a better performing diesel engine oil was available—all the way from API CD to API CI+4.</p>
<p>Today diesel engine oils look like the example shown in figure 1. From 20 to 30% of modern diesel engine oil is additives designed to improve performance in key areas. These additives are carefully engineered mixtures of compounds formulated to pass the various diesel engine tests which define a new lube oil specification like CI+4.</p>
<p> </p>
<hr width="70%">
<table width="380" border="0" align="center" cellpadding="5" cellspacing="0">
<tr>
<td width="45" bgcolor="#EBEBEB"><center>
<font size="2" face="Arial, Helvetica, sans-serif"><strong>1</strong></font>
</center></td>
<td width="20" height="40"><center>
</center></td>
<td height="40" colspan="2"><strong><font size="3" face="Arial, Helvetica, sans-serif">Typical Diesel Engine Oil Consumption </font></strong></td>
</tr>
<tr>
<td></td>
<td width="20"> </td>
<td width="212"><font size="2" face="Arial, Helvetica, sans-serif">• Base Oils:</font></td>
<td width="225"><font size="2" face="Arial, Helvetica, sans-serif">69-80%</font></td>
</tr>
<tr>
<td></td>
<td width="20"> </td>
<td><font size="2" face="Arial, Helvetica, sans-serif">• Performance Package:</font></td>
<td><font size="2" face="Arial, Helvetica, sans-serif">15-20%</font></td>
</tr>
<tr>
<td></td>
<td width="20"> </td>
<td><font size="2" face="Arial, Helvetica, sans-serif">• Viscosity Modifier:</font></td>
<td><font size="2" face="Arial, Helvetica, sans-serif">5-10%</font></td>
</tr>
<tr>
<td> </td>
<td width="20"> </td>
<td><font size="2" face="Arial, Helvetica, sans-serif">• Pour Point Depressant:</font></td>
<td><font size="2" face="Arial, Helvetica, sans-serif">0-1%</font></td>
</tr>
</table>
<hr width="70%">
<p> </p>
<p>Pour point depressants are used to keep the oil fluid at very low temperatures. (They inhibit wax crystal formation.) Viscosity modifiers are used to make the oil thin out less as it is heated. This makes an oil which we call “Multigrade” and it simply means the multigrade oil acts like a thinner oil at low temperatures and a thicker oil at high temperatures. Multigrade diesel engine oils were a key part of the solution to the excessive oil consumption problem addressed by API formulation CE.</p>
<p>The performance additive package (see figure 2 is a mixture of 8­12 specialty chemicals, each of which is intended to impart specific properties to the oil’s performance. The important thing to remember here is that most additive chemicals (particularly detergents) deplete or wear out in service. This is one of the reasons why the oil must be changed. Life <em>was</em> good.</p>
<p> </p>
<hr align="center" width="70%">
<table width="697" border="0" align="center" cellpadding="5" cellspacing="0">
<tr>
<td width="39" bgcolor="#EBEBEB"><center>
<font size="2" face="Arial, Helvetica, sans-serif"><strong>2</strong></font>
</center></td>
<td width="16" height="40"><center>
</center></td>
<td height="40" colspan="2"><strong><font size="3" face="Arial, Helvetica, sans-serif">Typical Diesel Oil Performance Package </font></strong></td>
</tr>
<tr>
<td></td>
<td width="16"> </td>
<td width="290" valign="top"><dl>
<dt><font size="3" face="Arial, Helvetica, sans-serif" align="left">• Detergents</font></dt>
<dd><font size="2" face="Arial, Helvetica, sans-serif" align="left">Neutralize Combustion Acids<br>
Minimize Wear<br>
Inhibit Rust Formation<br>
Oxidation Inhibitor
</font></dd>
</dl></td>
<td width="293" valign="top"><dl>
<dt><font size="3" face="Arial, Helvetica, sans-serif" align="left">• Oxidation Inhibitors </font></dt>
<dd><font size="2" face="Arial, Helvetica, sans-serif" align="left">Retard Oil Decomposition<br>
Slow Deposit Formation
</font></dd>
</dl></td>
</tr>
<tr>
<td></td>
<td width="16"> </td>
<td valign="top"><dl>
<dt><font size="3" face="Arial, Helvetica, sans-serif" align="left">• Dispersants </font></dt>
<dd><font size="2" face="Arial, Helvetica, sans-serif" align="left">Prevent Agglomeration of Soot Particles<br>
Suspend Contaminants in Oil
</font></dd>
</dl></td>
<td valign="top"><dl>
<dt><font size="3" face="Arial, Helvetica, sans-serif" align="left">• Anti-Wear Agents </font></dt>
<dd><font size="2" face="Arial, Helvetica, sans-serif" align="left">Create Sacrificial Film Between Metal Parts<br>
Minimize Valve Train wear
</font></dd>
</dl></td>
</tr>
<tr>
<td height="44"></td>
<td width="16"> </td>
<td valign="top"> </td>
<td valign="top"><dl>
<dt><font size="3" face="Arial, Helvetica, sans-serif" align="left">• Foam Inhibitors </font></dt>
<dd><font size="2" face="Arial, Helvetica, sans-serif" align="left">Prevent Oil Foaming
</font></dd>
</dl></td>
</tr>
</table>
<br>
<hr align="center" width="70%">
<span class="columnheader"><p>So, What Did the EPA Do To Us?</p></span>
<p>Now, don’t take me wrong—I’m for a cleaner environment like everyone else is. The problem with the EPA is that they just decree which emissions will be reduced without once considering the cost, the technology needed or its effect on your operation. They refer to that as “Technology Forcing Legislation.” In the case of diesel engine oils, the EPA forced the adoption of a low-sulfate ash, phosphorus, and sulfur (low SAPS) oil whose technology hasn’t yet been proven extensively in the field.</p>
<p>Low SA (less than 1 percent weight) effectively places a limit on the amount of detergent which can be used in these oils. But diesels love detergents. In over 25 years of inspecting various diesel engines in the field, I’ve yet to see one which didn’t perform better on oils with higher levels of detergency.</p>
<p>Low P means the Feds placed a limit on the amount of Zincdithiophosphate (ZDP) additive which can be utilized. ZDP is the most effective oxidation inhibitor and anti-wear agent currently available. Additive manufacturers are now forced to use more expensive and less effective ashless oxidation inhibitors and anti­ wear agents.</p>
<p>Low S means the new oils can’t rely on some of the least expensive Sulfur-based oxidation inhibitors they used in the past. And, once again, many of the new ashless oxidation inhibitors haven’t been thoroughly field proven in heavily loaded trucks. Low S means more highly refined base oils, which is a positive thing. Average base oil quality is now significantly improved.</p>
<span class="columnheader"><p>So, What Oil Should I use?</p></span>
<p>If you have a diesel engine equipped with a DPF, you should probably use API CJ-4 oils. You really don’t have a choice unless you want to clean your particulate trap more frequently. Pay particular attention to oil change intervals. Interestingly, one of the major US fleets I deal with plans to utilize CI-4 oils and clean their traps more often. Their reasoning is, (1) we have very few 2007 engines in our fleet, and (2) we want to use only one diesel engine oil to minimize the chance for errors in our shops. I don’t think they will be alone! </p>
<p>If you don’t have an engine equipped with a DPF, by all means utilize an API CI-4 oil! Your engine will thank you for it! Most of the major oil suppliers to commercial fleets have already committed to having both oils available at least through 2009. They don’t like it, but their major customers are demanding the older oil be kept on the shelves.</p>
<p>I know that the major oil marketers are telling their customers that CJ-4 oils are backward compatible (you can use them in pre-2007 engines), and that is somewhat true. But if you use less detergent in an oil, your oil change interval should be shortened accordingly. Oil marketers don’t care if you have to change your oil more frequently—in fact, they love it! Remember oil companies are really in the business of moving as much base oil as possible. They love short oil change intervals.</p>
<p>In closing, remember to change your oil as frequently as possible, so we all can generate some more profits for those poor oil companies.</p>[/RAW]
<p>For those not familiar with Lubrizol, Lubrizol is one of a handful of companies that make and sell the additive package that goes into the finished product, one gallon lube oil jug.</p>
<p>More on John’s credentials: He holds several patents and has published many industry-related technical articles. He is a past Chairman of the Cleveland Section of the Society of Automotive Engineers (SAE) and both a Recognized Associate and a Silver Spark Plug (their highest honor) of the Technology and Maintenance Council of the American Trucking Associations. He is a recognized lubrication consultant to both the racing (NASCAR and NHRA) and trucking industries. </p>
<p>We are fortunate to have John’s article addressing the CJ-4 lube oil specifications.</p>
<span class="columnheader"><p>CI-4/CJ-4 DIESEL OILS<br>
What's a Guy Supposed to Buy?</p>
</span>
<p class="columnheader">A new diesel engine oil (API CJ-4) becomes commercial before year end 2006. It is important that you understand what API CJ-4 lube oil is (and isn’t), and why it was developed. Armed with the proper knowledge imparted by someone who isn’t trying to sell you something, you can then make an intelligent decision about which oil to use in your diesel engine. </p>
<center>
<hr align="center" width="400">
<em>It is important that you understand what API CJ-4<br>
lube oil is (and isn’t), and why it was developed.<br>
</em>
<hr align="center" width="400" noshade>
</center>
<p> First, let's discuss why this new oil was developed. The EPA will tighten their exhaust emissions thumbscrew on diesel engines starting January 1, 2007, to reduce particualte matter (PM) and oxides of Nitrogen (NOx) emissions even further. To meet these latest requirements most diesel engine manufacturers are resorting to the use of diesel particulate filters (DPFs). A DPF differs from the catalytic converters we have used for years on gasoline engines in that a DPF actually filters the <em>entire</em> diesel exhaust stream. </p>
<p>On the surface you wouldn’t think this would be a big deal— Europeans have been using DPFs for years. The difference is that Europeans don’t accumulate mileage like Americans and they will tolerate much more frequent service intervals. Our EPA has decreed that the new DPFs must go 150,000 miles before needing removal for cleaning. This means the soot collected in the DPF must be burned off in the exhaust system frequently if trap life is to exceed 150,000 miles without removal and cleaning. </p>
<p>I don’t have to tell you that diesel exhaust is relatively dirty. It consists of lots of soot (That’s what turns your oil black!) and unburned residues from both the fuel and the oil. Sulfur in the fuel can significantly hamper DPF performance. That’s why we’re getting the new ultra low sulfur diesel (ULSD) fuel this fall (more about ULSD fuel later). Phosphorus and sulfur in the lube oil can shorten DPF cleaning intervals considerably. Phosphorus (P) can “glaze over” and plug the tiny holes in the DPF, making the openings effectively smaller and quicker to plug. Sulfur (S) can “mask” the DPF, making it temporarily less effective. Sulfated Ash (SA) in the lube is thought to build up deposits on the DPF over time. These deposits that originate from diesel fuel and lube oil then make the DPF effectively smaller and quicker to plug. </p>
<span class="columnheader"><p>A Little Lube Oil History</p></span>
<p>Before we talk about what the additive industry and the oil companies have done to meet the EPA’s latest directive, we need a brief lube oil history lesson. Years ago diesels were operated on refined crude oils containing virtually no additive chemistry. As power density increased oil companies found they needed to add specific chemical compounds to the oil to provide performance attributes that crude oils couldn’t deliver. The additive industry was born! </p>
<p>Traditionally, each new diesel engine oil specification was issued because available oils couldn’t provide the lube oil performance needed. For example, API CE was issued to create oils which solved an oil consumption problem in Cummins NTC-400 engines. For fifty years each new diesel engine oil specification meant a better performing diesel engine oil was available—all the way from API CD to API CI+4.</p>
<p>Today diesel engine oils look like the example shown in figure 1. From 20 to 30% of modern diesel engine oil is additives designed to improve performance in key areas. These additives are carefully engineered mixtures of compounds formulated to pass the various diesel engine tests which define a new lube oil specification like CI+4.</p>
<p> </p>
<hr width="70%">
<table width="380" border="0" align="center" cellpadding="5" cellspacing="0">
<tr>
<td width="45" bgcolor="#EBEBEB"><center>
<font size="2" face="Arial, Helvetica, sans-serif"><strong>1</strong></font>
</center></td>
<td width="20" height="40"><center>
</center></td>
<td height="40" colspan="2"><strong><font size="3" face="Arial, Helvetica, sans-serif">Typical Diesel Engine Oil Consumption </font></strong></td>
</tr>
<tr>
<td></td>
<td width="20"> </td>
<td width="212"><font size="2" face="Arial, Helvetica, sans-serif">• Base Oils:</font></td>
<td width="225"><font size="2" face="Arial, Helvetica, sans-serif">69-80%</font></td>
</tr>
<tr>
<td></td>
<td width="20"> </td>
<td><font size="2" face="Arial, Helvetica, sans-serif">• Performance Package:</font></td>
<td><font size="2" face="Arial, Helvetica, sans-serif">15-20%</font></td>
</tr>
<tr>
<td></td>
<td width="20"> </td>
<td><font size="2" face="Arial, Helvetica, sans-serif">• Viscosity Modifier:</font></td>
<td><font size="2" face="Arial, Helvetica, sans-serif">5-10%</font></td>
</tr>
<tr>
<td> </td>
<td width="20"> </td>
<td><font size="2" face="Arial, Helvetica, sans-serif">• Pour Point Depressant:</font></td>
<td><font size="2" face="Arial, Helvetica, sans-serif">0-1%</font></td>
</tr>
</table>
<hr width="70%">
<p> </p>
<p>Pour point depressants are used to keep the oil fluid at very low temperatures. (They inhibit wax crystal formation.) Viscosity modifiers are used to make the oil thin out less as it is heated. This makes an oil which we call “Multigrade” and it simply means the multigrade oil acts like a thinner oil at low temperatures and a thicker oil at high temperatures. Multigrade diesel engine oils were a key part of the solution to the excessive oil consumption problem addressed by API formulation CE.</p>
<p>The performance additive package (see figure 2 is a mixture of 8­12 specialty chemicals, each of which is intended to impart specific properties to the oil’s performance. The important thing to remember here is that most additive chemicals (particularly detergents) deplete or wear out in service. This is one of the reasons why the oil must be changed. Life <em>was</em> good.</p>
<p> </p>
<hr align="center" width="70%">
<table width="697" border="0" align="center" cellpadding="5" cellspacing="0">
<tr>
<td width="39" bgcolor="#EBEBEB"><center>
<font size="2" face="Arial, Helvetica, sans-serif"><strong>2</strong></font>
</center></td>
<td width="16" height="40"><center>
</center></td>
<td height="40" colspan="2"><strong><font size="3" face="Arial, Helvetica, sans-serif">Typical Diesel Oil Performance Package </font></strong></td>
</tr>
<tr>
<td></td>
<td width="16"> </td>
<td width="290" valign="top"><dl>
<dt><font size="3" face="Arial, Helvetica, sans-serif" align="left">• Detergents</font></dt>
<dd><font size="2" face="Arial, Helvetica, sans-serif" align="left">Neutralize Combustion Acids<br>
Minimize Wear<br>
Inhibit Rust Formation<br>
Oxidation Inhibitor
</font></dd>
</dl></td>
<td width="293" valign="top"><dl>
<dt><font size="3" face="Arial, Helvetica, sans-serif" align="left">• Oxidation Inhibitors </font></dt>
<dd><font size="2" face="Arial, Helvetica, sans-serif" align="left">Retard Oil Decomposition<br>
Slow Deposit Formation
</font></dd>
</dl></td>
</tr>
<tr>
<td></td>
<td width="16"> </td>
<td valign="top"><dl>
<dt><font size="3" face="Arial, Helvetica, sans-serif" align="left">• Dispersants </font></dt>
<dd><font size="2" face="Arial, Helvetica, sans-serif" align="left">Prevent Agglomeration of Soot Particles<br>
Suspend Contaminants in Oil
</font></dd>
</dl></td>
<td valign="top"><dl>
<dt><font size="3" face="Arial, Helvetica, sans-serif" align="left">• Anti-Wear Agents </font></dt>
<dd><font size="2" face="Arial, Helvetica, sans-serif" align="left">Create Sacrificial Film Between Metal Parts<br>
Minimize Valve Train wear
</font></dd>
</dl></td>
</tr>
<tr>
<td height="44"></td>
<td width="16"> </td>
<td valign="top"> </td>
<td valign="top"><dl>
<dt><font size="3" face="Arial, Helvetica, sans-serif" align="left">• Foam Inhibitors </font></dt>
<dd><font size="2" face="Arial, Helvetica, sans-serif" align="left">Prevent Oil Foaming
</font></dd>
</dl></td>
</tr>
</table>
<br>
<hr align="center" width="70%">
<span class="columnheader"><p>So, What Did the EPA Do To Us?</p></span>
<p>Now, don’t take me wrong—I’m for a cleaner environment like everyone else is. The problem with the EPA is that they just decree which emissions will be reduced without once considering the cost, the technology needed or its effect on your operation. They refer to that as “Technology Forcing Legislation.” In the case of diesel engine oils, the EPA forced the adoption of a low-sulfate ash, phosphorus, and sulfur (low SAPS) oil whose technology hasn’t yet been proven extensively in the field.</p>
<p>Low SA (less than 1 percent weight) effectively places a limit on the amount of detergent which can be used in these oils. But diesels love detergents. In over 25 years of inspecting various diesel engines in the field, I’ve yet to see one which didn’t perform better on oils with higher levels of detergency.</p>
<p>Low P means the Feds placed a limit on the amount of Zincdithiophosphate (ZDP) additive which can be utilized. ZDP is the most effective oxidation inhibitor and anti-wear agent currently available. Additive manufacturers are now forced to use more expensive and less effective ashless oxidation inhibitors and anti­ wear agents.</p>
<p>Low S means the new oils can’t rely on some of the least expensive Sulfur-based oxidation inhibitors they used in the past. And, once again, many of the new ashless oxidation inhibitors haven’t been thoroughly field proven in heavily loaded trucks. Low S means more highly refined base oils, which is a positive thing. Average base oil quality is now significantly improved.</p>
<span class="columnheader"><p>So, What Oil Should I use?</p></span>
<p>If you have a diesel engine equipped with a DPF, you should probably use API CJ-4 oils. You really don’t have a choice unless you want to clean your particulate trap more frequently. Pay particular attention to oil change intervals. Interestingly, one of the major US fleets I deal with plans to utilize CI-4 oils and clean their traps more often. Their reasoning is, (1) we have very few 2007 engines in our fleet, and (2) we want to use only one diesel engine oil to minimize the chance for errors in our shops. I don’t think they will be alone! </p>
<p>If you don’t have an engine equipped with a DPF, by all means utilize an API CI-4 oil! Your engine will thank you for it! Most of the major oil suppliers to commercial fleets have already committed to having both oils available at least through 2009. They don’t like it, but their major customers are demanding the older oil be kept on the shelves.</p>
<p>I know that the major oil marketers are telling their customers that CJ-4 oils are backward compatible (you can use them in pre-2007 engines), and that is somewhat true. But if you use less detergent in an oil, your oil change interval should be shortened accordingly. Oil marketers don’t care if you have to change your oil more frequently—in fact, they love it! Remember oil companies are really in the business of moving as much base oil as possible. They love short oil change intervals.</p>
<p>In closing, remember to change your oil as frequently as possible, so we all can generate some more profits for those poor oil companies.</p>[/RAW]