You can check the level anytime after an overnight shutdown. I am not sure why the liquid is not returning unless there is/was a restriction in the bottle. It is possible the cap is bad, you might try another one. Maybe the vacuum valve is somehow bad. The radiator should be full after an overnight shutdown. I doubt there is any issue with the head or head gasket as long as there is no cross contamination of oil or coolant. If there is an external leak I would think you would see it, however sometimes they can be so small the leak seems to vanish. The 24 valve is bad about leaking from the right front corner of the head gasket, check that area real good, use a flash light.