I've used several types of refrigants in automotive, especially the older trucks now that R-12 is not so easily available. R-22, the older type of freon used for almost a century in home appliances, is becoming harder to find as well. It and R-12 were designed to be used with an expansion valve type system, where gasses are restricted by temperature of a probe inserted in the evaporator coils. An orifice is used with R-134, which lets the compressor run more, allowing it to wear faster, build more heat, and the dealer to sell more parts, and Dupont to make more R-134 since their patent has run out on R-12... ... oh, wait, that would make logical sense... . how about R-134 is more safe for the environment? Whatever. I've not used DuraCool, or know what it's chemical composition is. The biggest problem with reverse flow heat systems, is the lack of need. They are readily used in residential air, but in automotive, why heat the passenger compartment with freon, when you have hot engine coolant so readily available, and you don't have to turn a compressor to get it? As for it running on the defrost mode, I don't like that, as there are often times when I don't need it. If I wanted the compressor on, I'd switch it on, but then, I'm too stupid to know when I REALLY need it, so some engineer decided to do it for me..... and remind to take my key out of the ignition and turn off my lights, too... ... .
As for a solar heater, I doubt enough energy can be developed to pump refrigant at a high enough capacity to make it feasible. It takes a lot of energy to build enough head pressure to liquify the freon, then pass it through a cooler to a small orifice, allowing it vaporize, absorbing energy and cooling the air passed over it.
In residential use, reverse heating with freon is called Heat-Pump by Trane..... ever see an outside unit frozen into a solid block of ice in the winter? That's a heat-pump. They really don't generate enough heat unless you live in a really mild climate.