The printing on the tire doesn't use the word "cap plies" That's just the way they are referred to generally. Anything beyond the basic "sidewall 2 plies polyester" , "tread 2 plies polyester + 2 piles steel" would be cap plies. I've only seen two types of fiber used in cap plies, nylon and kevlar (aka aramid).
Please note: The plies are NOT additive between sidewall and tread. The "two plies polyester" shown in the tread are THE SAME TWO PIES that form the sidewall. The two polyester sidewall plies go radially from bead to bead, so they are also under the tread. Steel belts and cap plies go around the circumference, over the top of the sidewall plies. If you took a core sample through the tread of a common 1-cap-ply tire, you would see 1 nylon cap ply on top, followed by 2 steel belts, then the two polyester "radial" plies. This is a total of 5 plies under the tread, not 7.
I have not ever seen a modern light-truck tire with more than 6 plies under the tread. There are also some tires that use all-steel cord for very high strength. I haven't used any of those. They seem to be fairly uncommon on light trucks. I'm guessing they are used more on large, heavy over-the-road trucks. I would expect the ride from those to be _very_ rough!