It is intertesting to see how coolant temp and engine oil temp can diverge at times. Senders mounted in the pan seem to suffer from the heat sink effect, that is why (I suspect) that Mag Hytec mounted the differential temperature sender in the top on the cover, that way you get operational oil temp rather than oil that has cooled (heat sink effect) by the aluminum cover.
Yes, Synchromax is the suggested oil for use in your transfer case. It is a much better lube than ATF IMO.
Oil change intervals are somewhat debateable, I run 30k miles in the manual transmission and have been changing the transfer case at the same time. But I think that is too often for the transfer case, I'm going to try 50k mile intervals on the transfercase with an oil level check at each engine oil change. The transfer case dosent hold much oil unless you have the PTO verson and a Fastcooler installed.