As far as rotating tires on a 3500... . see page 144 in the owner's manual (2001) for the DC diagram. I have been doing this every 5K miles or so, and tires look nearly new with about 16K miles on them.
By the way, 65 psig front, 45 psig back unloaded seems best for my truck. I liked the idea in the earlier post about measuring tire temperture differences across the tread. Thats how real tire technicians figure out pressure (and alignment) on race cars.
Bob