Hemi,
If your DVC driver is 8ohm, then yes your statement: "If a got an 8 ohm DVC woofer (paralell wired), then I could use the 2 rear channels in a bridged mono mode, and the amp would see 4 Ohms?" is correct. Two 8ohm VC wired in parallel would create a 4ohm load.
"How much difference would I notice with the Sub gettting 400 watts as opposed to 200 watts at low to mid volume?"
In low to mid volume you will probably notice very little difference, it is when you start getting a little carried away

is when you will hear a difference. The driver will obviously have the ability to play louder with the added wattage, but more importantly it will play cleaner to a higher level of volume (this is assuming the driver is rated for 400 watts RMS to begin with). You won't have to push the amp as hard (and cause it to "clip") to achieve higher levels of volume. The driver with 200 watts will distort sooner (at a lower sound level) than if the driver was being pushed with 400 watts. Again this applies to when your really get on the system. I am finding this a little difficult to explain, but hopefully it is making sense. Let me try to use an example: Say you have a driver rated at 500 watts RMS, and you have an amp rated at 100 watts RMS. You could very easily damage the 500 watt driver with only 100 watts of power. This is because you are forcing the amp to work very hard and possibly distorting and damaging the driver.
To answer your question, at low to moderate volumes you probably won't even notice a difference. This is becasue you have adjusted your gains on the amp properly to distrubute the sound (between doors and sub) to what in your opinion is "evenly". Obviously you don't want a ton of bass at a low volume level, otherwise the lyrics will drown out. As I already said, the difference will be in higher volumes only.
I hope that all makes sense.
-Ryan
Just curious what you are running in the doors @ 100 watts a channel.