Synthetic oil as a motor oil
The majority of oil lubricants, including many motor oils, are mineral oil distillates of crude oil. However, synthetic motor oils also have a share in the market. Historically, synthetic motor oils have been made from the following classes of lubricants.
Polyalpha-olefin (PAO) = American Petroleum Institute (API) Group IV base oil
Synthetic esters, etc = API Group V base oils (non-PAO synthetics, including diesters, polyolesters, alklylated napthlenes, alkyklated benzenes, etc. )
In the last decade of the 20th century, hydrocracked and/or isomerized (Group III) base oils began to be used in motor oils. These oils are also designated as "synthetic" in the United States.
Automotive Use History
Although in use in the aerospace industry for some years prior, synthetic oil first became commercially available in an API-approved formula for automobile engines when the French Oil company MOTUL introduced a commercial ester-based synthetic-oil in 1971. Other early synthetic motor oils included All-Proof, a 10W-50 polyolester-based motor oil introduced in 1970, Amsoil, introduced in 1972 (with a diester-based 10W-40 formula developed by Hatco) and Mobil 1, introduced in 1974 (with a PAO-based 5W-20 formula).
Required Applications
Many modern high-performance vehicles specify synthetic motor oils. Some manufacturer specifications include:
GM-LL-B-025 (diesel engines)
GM-LL-A-025 (petrol or gasoline powered engines)
VW 502. 00/505. 00/503. 01 (includes both diesel and petrol or gasoline engines)
MB 229. 5 (DaimlerChrysler)
BMW Longlife 01
Honda HTO-06
Porsche Approval list 2002
Some Briggs & Stratton small engines.
Various motor oils made from Group III, Group IV, and/or Group V base oils are on the market that meet one or more of these manufacturer specifications.