The spyntec kit will have zero effect on transfer case shifting if you are stopped, which you should be to go into low range with the hubs in "free".
The below procedures are from the owners manual. If your hubs are in "free"you need to use the alternate method, if they are in "lock" you can use either.
Preferred Procedure
1. With engine RUNNING, slow vehicle to 2 to 3 mph (3
to 5 km/h).
2. Shift the transmission into NEUTRAL (depress clutch
on manual transmissions).
3. While still rolling, rotate the transfer case control
switch to the desired position.
4. After the desired position indicator light is ON (not
flashing), shift transmission back into gear (release clutch
on manual transmissions).
Alternate Procedure
1. Bring the vehicle to complete stop.
2. With the key ON and the engine either OFF or
RUNNING, shift the transmission into NEUTRAL (depress
clutch on manual transmissions).
3. Rotate the transfer case control switch to the desired
position.
4. After the desired position indicator light is ON (not
flashing), shift transmission back into gear (release clutch
on manual transmissions).
NOTE: If steps 1 or 2 of either the Preferred or Alternate
Procedure are not satisfied prior to attempting the shift
then the desired position indicator light will flash continuously
while the original position indicator light is
ON, until all requirements have been met.
NOTE: The ignition key must be ON for a shift to take
place and for the position indicator lights to be operable.
If the key is not ON then the shift will not take place and
no position indicator lights will be on or flashing.