Look I don't have personal experience with Dodges and 5ers but I expect there's two answers to this.
The long answer is that you can calculate the load your 5er will pull when charging/running, the load from all add-ons to the truck, etc. You can then find out what the truck's 'base' load is so you know how much spare amperage there is in the 180A unit. Compare the two and you'll know whether the 220A is needed.
The short answer is that over time you will always want more power: phones, ipads, laptops, torches, light bars, decorative LEDS, fridges, accessories, accessories, accessories. It will never be cheaper to upgrade your alternator than right now. I forget how much the extra is but it's a trivial additional cost on top of the truck as a whole. Go for it.
To answer your specific question, yes it will give you a bunch more charge for your 5er. I don't know how you guys set things up over there, but an extra 40 amps is a lot of juice.
A grossly oversimplified example: The more amperage your truck can provide to the 5er, the faster it will charge, especially if it's running on lithium batteries. Say the truck and all its accessories barring the 5er needs 140A, so that the 180A unit has a 'spare' 20A for the 5er. If you'd drained say 10A for 12 hours overnight in the 5er, that's 120 A/h you've used and need to get back into the 5er's batteries. At 20A, pretending 100% efficiency for simplicity, that's 6 hours to recharge the 120 A/h. (Actually it will be more than 6 hours, especially if the 5er has lead acid batteries, because there are limits to how fast lead-acids can absorb charge especially as they start getting full.) Now switch to the 220A unit. All else being equal you now have 60A to play with. For 120 A/h that's just 2 hours' charging. Now this is much oversimplified, because nothing is 100% efficient so there is power loss at every step of the process. Also each different type of battery has a different charging profile. Lead acids can only accept high rates of charge when nearly empty. Lithium batteries are (a) more linear, ie. the rate of charge doesn't fall off as fast as they approach full; and (b) can accept much higher absolute charge rates than lead acid anyway, so for both reasons a power surplus will benefit you more with lithiums. But either way, whatever your batteries, more amperage on tap will usually mean a faster charge.
BTW on some options you can (or at least used to be able to) specify a whole
additional 220A alternator. Snow plow prep I think. Juice galore!
Good luck with the purchase!