Each sensor's (transmitter) broadcast is uniquely coded so that the wireless control module (WCM) can monitor the state of each of the sensors on the four rotating road wheels. The WCM can automatically learn and store the sensor's ID while driving "within 10 minutes continuously above 15 m.p.h. (24 Km/h)" after a sensor has been replaced. The vehicle must be stationary for more then 20 minutes in order to initiate the learning sequence.
The sensor IDs can also be programmed using the TPM-RKE Analyzer Tool. Scan each TPM sensor at each road wheel, and store each Sensor ID in the correct location. (LEFT FRONT, LEFT REAR, RIGHT FRONT, and RIGHT REAR) Connect the TPM-RKE Analyzer Tool to the Scan Tool. Then follow the programming steps outlined in the diagnostic Scan Tool for "Program Tire Pressure Sensor ID w/ TPM Tool" under "MISC" for the "WCM/WIRELESS CONTROL MODULE".
Either way, it has to be learned because each sensor has a unique ID.
Good luck.