I posted this in another thread. It is directly out of the manuals which I quote by title and page.
What you are going to read here, is quoted directly out of the following BOSCH book, Diesel-Engine Management, 4th Edition by Robert Bosch Gmbh, October 2005. This is from page 48 and 49, under Alternative Fuels.
Food for thought guys. Information is always valuable.
Quote begins PG 48. Alternative fuels for diesel engine include biogenic fuels, and, in a wider sense, fossil fuels that are not produced on the basis of crude oil. This included mainly esters that are derived from organic oils.
Alcohol fuels (methanol and ethanol) are only used in diesel engines to a minor extent, and only as an emulsion together with diesel fuel.
Fatty-Acid Methyl Ester (FAME)
Fatty-Acid Methyl Ester (Fame) – commonly known as biodiesel – is the generic term applied to vegetable or animal oils and greases which have been transesterified with methanol. FAME is produced from various raw materials, mainly from rape seed oil (Rape Seed Oil Methyl Ester (RME) Europe), or soya (Soya Methyl Ester (SME), U. S. A. ). There are also sunflower and palm esters (Used Frying Oil Methyl Esters (UFOME), and beef tallow esters (Tallow Methyl Esters (TME)), but these are mostly used in conjunction with other FAMEs. Ethanol can also be transesterified instead of methanol, as in Brazil to produce soya ethyl ester. FAME is either used in pure form (B100, i. e. 100% biodiesel), or it is mixed with diesel fuel to maximum FAME proportion of 5% to from Blend B5. B5 is permitted as a diesel fuel in compliance with EN590.
Since the use of low-quality FAME may lead to malfunctions or damage to the engine and fuel-injection system, FAME specifications are controlled at European level (EN14214). It is essential, in particular, to ensure good aging stability (oxidation stability) and to eliminate contamination caused by the process. FAME must satisfy European Standard EN 14214, regardless of whether it is used directly as B100, or as an additive in diesel fuel. The B5 blend created by FAME additives must also comply with the requirements for pure diesel fuel (EN590).
The production of FAME is uneconomical in comparison with mineral-oil-based diesel fuels and must be heavily subsidized (exemption from mineral-oil tax) in Germany.
Pure, unesterified vegetable oils are no longer used in direct-injection diesel engines since they cause considerable problems, mainly due to their high viscosity and extreme nozzle coking.
PG 49, Emulsions
Emulsions of water or ethanol in diesel fuels are undergoing trials at a number of different institutes, Water and alcohols are difficult to dissolve in diesel. Emulsifiers are required to keep the mixture stable and prevent it from demulsification. Wear- and corrosion-inhibiting measures are also necessary. The use of emulsifiers reduces soot- and nitrogen-oxide emissions since the combustion mixture is cooler due to the water content.
Their use to date has been restricted to vehicle fleets which, for the most part, are equipped with in-line fuel-injection pumps. Other fuel-injection systems are either unsuitable for operations with the emulsifiers, or no trials have been made using them.
End of Quote