From what I can tell reading the service manual, you would have to add an additional blend door, and blend door actuator. I have attached that section of the manual for your reference. I have the dual zone and like it very much. There are no temp sensors, it's just two sliders - one passenger temp, and one driver temp. It appears to be do-able and maybe even feasable.
Here's the excerpt:
BLEND DOOR ACTUATOR
DESCRIPTION
The blend door actuators are reversible, 12-volt
Direct Current (DC), servo motors. Models with the
single zone heater and air conditioner system have a
single blend air door, which is controlled by a single
blend door actuator. Models with the optional dual
zone front heater and air conditioner system have
dual blend air doors, which are controlled by two
blend door actuators. The single zone blend door
actuator is located on the driver side end of the heater-
A/C housing unit, close to the dash panel. In the
dual zone system, the same blend door actuator used
for the single zone system becomes the driver side
blend door actuator, and is mechanically connected to
only the driver side blend air door. In the dual zone
system, a second separate blend door actuator is also
located on the top of the heater-A/C housing unit and
is mechanically connected to only the passenger side
blend air door.
The blend door actuators are interchangeable with
each other, as well as with the actuators for the
mode door and the recirculation air door. Each actuator
is contained within an identical black molded
plastic housing with an integral wire connector
receptacle. Two integral mounting tabs allow the
actuator to be secured with two screws to the heater-
A/C unit housing. Each actuator also has an identical
output shaft with splines that connects it to the linkage
that drives the proper blend air door. The blend
door actuators do not require mechanical indexing to
the blend door linkage, as they are electronically calibrated
by the heater-A/C control module. The blend
door actuators cannot be adjusted or repaired and, if
damaged or faulty, they must be replaced.