I'm also in the HVAC world and a lic. contractor, and also taught for a couple of years. You couldn't of said it better, but what I do to help my AC catch up to high cabin heat, is to crack the windows open slightly and open the system to outside air, which causes a positive air condition in the cab and pushes out the high heat built up in the cab. Then I select recirculation and keep it there until I get out. I guess you can say this helps in relieving stress on the system, seeing how the outside air is cooler than the cabin air, therefore it helps keep the refrigerant pressures lower. But that isn't why I do it, I do it to cool the cab quicker.
On my 04. 5 CTD I had the issue of the vent door from day one, my wife would always complain of being warmer and when climbing grades we would get the diesel smell from the big rigs. When I complained to the dealer, I was told that they are required to have a little fresh air entering the cab. That was bogus, but I believed it at the time, because of the fresh air requirements on building AC systems. When my vent door failed completely it was out of warranty and they paid for half the cost. Once the vent door was fixed, all the issues my wife complained about went away, to include no more diesel smell on grades.