I stumbled on the issue of optimum RPM in this thread while researching another question.
Basically, the flat torque curve in the 24v 5. 9 HPCR from 1500 to 2500 gives you a large window of possible maximum fuel economy. What will affect it most is ambient and/or forcibly pushed wind (a function of speed), and the particular gearing you are running at a given speed.
I am running a Gear Vendor overdrive in a 2006 6-speed, and have constructed many spreadsheet graphs reflecting the impact of torque on available speed ranges in different gears. Look at the pdf file, which shows in one graph the speed ranges available in each gear, regular and overdrive, and in another graph the likely hp output as a function of torque. (The other two pages are raw numbers used to create the spreadsheet graphs).
At present, I am making 20-21 mpg at 75 mph, 1900 rpm, on I-80 back and forth across Nevada. Realize, however, that I was forced into buying the Gear Vendor unit because Dodge did not offer a 3. 55 axle in 2006. which is what I normally would use with a 6-speed manual, so I am stuck with the factory 3. 74. Those of you who have an automatic have a transmission with intrinsically higher gearing than the G56, so you normally get higher mileage by default, without having to resort to an add-on overdrive.