There is no seperate overdrive gears in the transmission, and there is no real size constraint to getting other gears, its just what works out.
A 48RE has a typical compound planetary gearset. I think the Ring gear may be about 74 tooth, the sun gears are 30 in the first and 32 teeth in the second. Somebody may have the exact count.
The two planetary gearsets work together to get the needed ratios. This gives a ratio of 2. 466:1 in first, 1. 44:1 in second, 1:1 in third and an overdrive of . 698:1.
This is pretty close to the spec ratios. of 2. 45 / 1. 45 / 1 / . 69
The point being is that you can't change one ratio without affecting the other two. The OD ratio as well ast the others are a compromise in gearing. A good balanced transmission that is strong enough. At least this part (planetary set) doesn't seem to fail very often.
If someone could machine something like 80/26/28 planetary gear set they would have very close 2nd through 5th of an NV4500 or 2,4,5,6 in an NV5600. I don't know how well that would work or even if it could be done or be strong enough. The Ring would be too thin with teeth too small, and the suns would be too small. This would probably be too fragile and not hold the torque.