The parking brake uses the main shoes unless you have rear disc brakes than there is a second set of e-brake shoes in addition to the rear pads... If your where it can freeze, its not uncommon for the brake cable to freeze with moisture in the inner cable... in the winter here in Spokane we don't use the parking brake for fear of it freezing... on the larger trucks we carry a rubber snubber for putting under the tire if necessary... But the truck is left in gear, or P as the case might be... .
If you can smell the brake shoes and it was that way for more than 10 minutes or so, there is the chance that you've cooked the resin out of the brake shoe, in which case they are now scrap... once the resin is damaged they will eventually fall apart... the resin both bonds some shoes to the steel and a different resin holds the raw materials in the brake shoe or brake pad chemical mix.
I'm not speaking of a bonding resin that holds the shoe to the backing plate but I'm speaking of both the bonding resin and the resin that holds the fabric together in the brake lining its self... In both cases the resins will start to fail at exposure to temperatures above 500*F and will de-bond from the steel shoe if they are bonded shoes above the 600*F range based on the quality of the bonding resin used...
Most disc brake pads start to fail in the 750*F ranged, again based on the quality of the bonding resin... When I ran the shop, we only used a high end bonding resin, something with a failure above 650*F when correctly applied and cured in a bonding oven... .
One thing to remember that a inexpensive bonding resin is under $150 a 5 gallon bucket and a good resin is closer to $325 and has to be stored under refrigeration to maintain its life... We purchased it as a 5 gal container but a large production shop would get it by the barrel... .
Hope this answers your question... if you have others post them and I'll try and help. .