I rebuilt my NV4500 last winter after 5th gear wiggled off. Went with all new bearings, brass syncros, fully splined mainshaft, and SBC clutch. The trans has 18,000miles now, and still shifts noticibly stiffer than before the brass syncros. Still using the proper Castrol fluid. Shift is more similar to the 6spd. My original syncros had NO wear on them, at 94,000 miles. If I had it to redo, would definately stay with the fiber stock syncros.
My . 02 worth.
Jeff