I'd guess a detent spring(s) is worn, and not holding the blocker ring in place like it should. Or something in your top isnt sliding the shift fork far enough when you go into 5th. My 91 popped out of first letting off the pedal, and my 92 pops out of second at will.
The synchro itself will only help in the shifting/ lack of grinding, not holding in gear.
Daniel