Been using the Peak BlueDEF for more than three years, but used the SuperTech (Wal-Mart "house brand") once. Although it appeared to be OK, I did have a problem a few thousand miles later in which the DEF inject became rather nasty. The dealership tech cleaned it to like new and it has been perfect ever since. While I do not blame the cheaper DEF, the possibility remains that I could have gotten a bad batch.
The Service Manager (very experienced and knowledgeable with all things Diesel) suggested that I:
1.) Verify the date code on the box when purchasing DEF... don't buy and use expired stuff
2.) Do not "top it off" unless you are going to be using a lot of it in a short period of time... wait until it gets down to less than half, then add a 2.5-gallon jug of the stuff.